Reversible addition–fragmentation chain transfer depolymerization of poly(methyl methacrylate) in toluene

Controlled depolymerizations of poly(methyl methacrylate) (PMMA) via reversible addition fragmentation chain transfer (RAFT) reach higher yields in some solvents rather than others, and the exact reasons are not fully understood. PMMA was synthesized with trithiocarbonate (TTC) and dithiobenzoate (D...

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Bibliographic Details
Published in:Polymer chemistry 2025-11, Vol.16 (44), p.4812-4827
Main Authors: Bones, Don X, Kumar, Adarsh, Nelson, Emily, Fofie, Bryanna, Hoy, Erik P, Gramlich, William M
Format: Article
Language:English
Subjects:
Chain transfer
Depolymerization
Fragmentation
Monomers
Polymethyl methacrylate
Solvents
Toluene
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