Algal biochar: A natural solution for the removal of Congo red dye from textile wastewater

• Published in: Journal of the Taiwan Institute of Chemical Engineers 2024, Vol.166, p.105312, Article 105312
• Main Authors: Khan, Abdul Ahad, Naqvi, Salman Raza, Ali, Imtiaz, Farooq, Wasif, Anjum, Muhammad Waqas, AlMohamadi, Hamad, Lam, Su Shiung, Verma, Meenakshi, Ng, Hui Suan, Liew, Rock Keey
• Format: Article
• Language: English
• Subjects: Adsorption; Algae-derived biochar; Artificial neural network; Cango red dye; Central-composite design; Chemical Engineering; Kemiteknik
• ISSN: 1876-1070; 1876-1089
• DOI: 10.1016/j.jtice.2023.105312

•Algal-derived biochar; an effective adsorbent for removing CR dye.•Evaluation of the efficacy of CR is determined using RSM.•Non-linear adsorption isotherm and kinetics model depicted removal mechanism.•Application of ANN to validate the removal efficacy and kinetics of CR dye. The present study was aimed at synthesizing algae-derived biochar to examine its effectiveness and adsorption capacity to remove Congo red dye. The independent variables such as dye concentration, adsorbent dose, and adsorption time were optimized by using a central composite design (CCD). An adsorption experiment was conducted to evaluate equilibrium using a detailed experimental design and characterized through XRD, TGA, SEM, EDX, and FTIR analysis. This paper also focuses on evaluating non-linear adsorption isotherm and kinetics to describe the adsorption mechanism along with applying an Artificial neural network to validate the removal efficiency. The maximum Congo red removal efficiency (96.14 %) and maximum adsorption capacity of algal biochar (186.94 mg/g) were achieved with the optimized parameters of 1 mg/L of dye concentration, 0.1 g of adsorbent dose, and 240 min of contact time. Adsorption behavior was well described by Langmuir isotherm and Pseudo-nth order. A multilayer perceptron (MLP) MLP 2–5–1 structure best validates the response. Overall, the study sheds light that Algal-derived biochar is a potential material for the elimination of Congo red dye and contributes to achieving sustainable development goals. [Display omitted]