Microwave Assisted Hydrothermal Carbonization and Solid State Postmodification of Carbonized Polypropylene

• Published in: ACS sustainable chemistry & engineering 2018-08, Vol.6 (8), p.11105-11114
• Main Authors: Adolfsson, Karin H, Lin, Chia-feng, Hakkarainen, Minna
• Format: Article
• Language: English
• Subjects: Carbonization; Hydrochar; Hydrothermal; Microwave; Plastic waste; Polypropylene
• ISSN: 2168-0485; 2168-0485
• DOI: 10.1021/acssuschemeng.8b02580

Functional carbon materials produced through a hydrothermal treatment of waste products have gained interest. Particularly, the method is considered more facile and green compared to conventional decomposition methods. Here, we demonstrated an upcycling of polypropylene (PP) waste to carbon materials by a microwave assisted hydrothermal treatment. The solid product obtained from the hydrothermal treatment was analyzed by multiple techniques to reveal the structure and the influence of processing conditions on PP degradation and hydrothermal carbonization. Chemical analyses showed the presence of carbonaceous material independent of acid amount (20 and 30 mL), temperature (210 and 250 °C), and time (20–80 min). A complete transformation of PP content to amorphous carbon required 60 min at 250 °C. The mass yield of the solid product decreased as a function of harsher processing conditions. At the same time, thermogravimetric analysis illustrated products with increasing thermal stability and a larger amount of remaining residue at 600 °C. The solid products consisted of irregular fragments and sheet-like structures. A solid state microwave process in air atmosphere was performed on a product with incomplete carbonization. The modification resulted in a decreased C/O ratio, and TGA analysis in nitrogen showed high thermal stability and degree of carbonization as indicated by the remaining residue of 86.4% at 600 °C. The new insights provided on the hydrothermal carbonization, and postmodification in air atmosphere, can catalyze effective handling of plastic waste by enabling transformation of low quality waste into functional carbon materials.