Oxygen production by solar vapor-phase pyrolysis of lunar regolith simulant

• Published in: Acta astronautica 2024-11, Vol.224, p.215-225
• Main Authors: Šeško, Rok, Lamboley, Kim, Cutard, Thierry, Grill, Laura, Reiss, Philipp, Cowley, Aidan
• Format: Article
• Language: English
• Subjects: Engineering Sciences; Lunar regolith; Oxygen extraction; Pyrolysis; Solar energy; Thermochemical modeling
• ISSN: 0094-5765; 1879-2030; 1879-2030
• DOI: 10.1016/j.actaastro.2024.08.009

The oxide-rich lunar surface regolith can be used to extract the oxygen needed for the future of lunar exploration efforts as a consumable for life-support systems and spacecraft propulsion. Various techniques for the extraction of oxygen have been developed already, with solar vapor-phase pyrolysis shown to be a promising yet understudied approach. In contrast to other techniques, it requires only locally available resources, such as unbeneficiated regolith, sunlight, and vacuum in order to liberate oxygen and oxygen-bearing molecules. This study presents experimental work conducted in a purpose-built solar-vacuum furnace showing the evaporation of sodium and iron from a regolith simulant sample and their deposition on the crucible surface. This is matched by the thermochemical equilibrium modeling done in FactSage, which analyzes the process at varying pressures down to ultra-high vacuum. It highlights the need for precise temperature and pressure control, as well as the impact of regolith composition on oxygen dissociation for an efficient extraction of molecular oxygen. •The thermochemical model of the process shows molecular oxygen yields of up to 14.1%.•Low-Titanium Mare is the most promising composition for oxygen production.•Vapor-phase pyrolysis of regolith was demonstrated in a small solar furnace.