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Global observations of middle atmospheric water vapour by the Odin satellite: An overview
Water vapour plays an important role for the chemistry and dynamics of the atmosphere. It is a strong greenhouse gas in the troposphere and contributes to cooling in the stratosphere. As the main source of chemically active HO x radicals, it is linked to many photo-chemical cycles controlling the co...
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Published in: | Planetary and space science 2007, Vol.55 (9), p.1093-1102 |
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Main Authors: | , , , , , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Water vapour plays an important role for the chemistry and dynamics of the atmosphere. It is a strong greenhouse gas in the troposphere and contributes to cooling in the stratosphere. As the main source of chemically active
HO
x
radicals, it is linked to many photo-chemical cycles controlling the composition of the middle atmosphere.
In order to improve our knowledge of the amount and variability of water in the middle atmosphere, the Sub-Millimetre Radiometer (SMR) on board the Odin satellite, launched in February 2001, observes several thermal emission lines of water vapour in the 486–581
GHz spectral range from the Earth's limb. Bands centred at 488.9 and 490.4
GHz are used to study water vapour and its isotopes, on the basis of four observation days per month. Vertical profiles of
H
2
O
16
,
H
2
O
18
, and HDO are retrieved between roughly 20 and 70
km in the stratosphere and mesosphere. A strong water vapour line at 556.9
GHz is simultaneously measured in a second band, providing information in the mesosphere and lower thermosphere between about 40 and 100
km. Measurements of
H
2
O
17
at 552.0
GHz in monthly intervals complete the picture of middle atmospheric water vapour provided by Odin/SMR.
The measurements of the isotope HDO in the 20–70
km altitude range allow to study the isotopic ratio of deuterium in stratospheric water vapour
(
D
/
H
)
, potentially supplying information on the origin of stratospheric water vapour: transport of tropospheric air through the tropical tropopause layer (TTL) versus in situ chemical production such as from methane oxidation. The unique measurements of the molecules
H
2
O
18
and
H
2
O
17
containing heavy isotopes of oxygen may provide a crucial test for our understanding of the complex chemical reaction mechanisms controlling the exchange of oxygen between water vapour and ozone. |
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ISSN: | 0032-0633 1873-5088 1873-5088 |
DOI: | 10.1016/j.pss.2006.11.021 |