Catalyst Stability Determines the Catalytic Activity of Non-Heme Iron Catalysts in the Oxidation of Alkanes

A series of iron(II) bis(triflate) complexes [Fe(L)(OTf)2] containing linear tetradentate bis(pyridylmethyl)diamine ligands with a range of ligand backbones has been prepared. The backbone of the ligand series has been varied from a two‐carbon linkage [ethylene (1), 4,5‐dichlorophenylene (2) and cyc...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2008-04, Vol.350 (6), p.883-897
Main Authors: England, Jason, Davies, Catherine R., Banaru, Maria, White, Andrew J. P., Britovsek, George J. P.
Format: Article
Language:English
Subjects:
alkanes
biomimetic synthesis
hydrogen peroxide
iron
N ligands
oxidation
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