Site‐Selective Direct Intermolecular C(sp3)−H Alkylation of Saccharides and Switching of Reaction Sites by Changing Photocatalysts

We developed a site‐selective intermolecular C(sp3)−H alkylation of saccharides with electron‐deficient alkenes using photocatalysis by anthraquinone and tetrabutylammonium decatungstate (TBADT). The main reaction site of anthraquinone‐catalyzed C(sp3)−H alkylation is determined by the weakness of t...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2023-08, Vol.365 (15), p.2577-2587
Main Authors: Li, Yanru, Kuninobu, Yoichiro
Format: Article
Language:English
Subjects:
Alkenes
Alkylation
anthraquinone
Anthraquinones
C(sp3)−H alkylation
Carbohydrates
decatungstate
Hydrogen atoms
Hydrogen bonds
Photocatalysis
Photocatalysts
saccharide
site-selective
Steric hindrance
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