Phosphine Catalyzed Enantioselective Cascade Reaction Initiated by Intermolecular Cross Rauhut‐Currier Reaction of Electron‐Deficient ortho‐Formyl Styrenes

The Rauhut‐Currier reaction generally employs α,β‐unsaturated carbonyl compounds and nitroalkenes as the substrates. Here we develop an enantioselective formal [4+2] annulation reaction, which is initiated by an intermolecular cross Rauhut‐Currier reaction between electron‐deficient ortho‐formyl‐sty...

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Bibliographic Details
Published in:ChemCatChem 2020-11, Vol.12 (21), p.5374-5377
Main Authors: Liang, Shu‐Yuan, Jiang, Bo, Xiao, Ben‐Xian, Chen, Zhi‐Chao, Du, Wei, Chen, Ying‐Chun
Format: Article
Language:English
Subjects:
Acrylonitriles
Aldehydes
Carbonyl compounds
Carbonyls
Cascade chemical reactions
cascade reaction
Chemical reactions
electron-deficient styrene
Enantiomers
enantioselective
phosphine catalysis
Phosphines
Rauhut-Currier reaction
Styrenes
Substrates
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