Estimate of the cation distribution for Ti-doped Ni0.68Fe2.32O4 spinel ferrites by fitting magnetic moments at 10 K

• Published in: physica status solidi (b) 2015-02, Vol.252 (2), p.411-420
• Main Authors: Xu, J., Ji, D. H., Li, Z. Z., Qi, W. H., Tang, G. D., Zhang, X. Y., Shang, Z. F., Lang, L. L.
• Format: Article
• Language: English
• Subjects: cation distribution; crystal structure; magnetic properties; quantum-mechanical potential barrier model; spinel ferrites; Ti doping
• ISSN: 0370-1972; 1521-3951
• DOI: 10.1002/pssb.201451216

Ti‐doped Ni0.68Fe2.32O4 spinel ferrite samples with nominal composition Ni0.68−0.8xTixFe2.32−0.2xO4 (0 ≤ x ≤ 0.312) were prepared using conventional ceramic methods. The samples exhibited a single‐phase cubic spinel structure. When the doping level had values x > 0.15, a transition temperature, TN, was found, below which the magnetization of the samples decreased with decreasing measurement temperature. This phenomenon indicates that an additional antiferromagnetic structure arises in the traditional spinel phase of ferrites resulted from Ti doping. Therefore, Ti ions appear in the form of Ti3+ and Ti2+ cations that have magnetic moments, rather than as Ti4+ cations without magnetic moment as assumed by many researchers. The dependence of the magnetic moments on the Ti doping level x at 10 K was fitted successfully using our quantum‐mechanical potential barrier model proposed earlier. In the fitting process, we assumed that the magnetic moments of the Ti cations were opposite to the direction of the Fe and Ni moments. According to the fitted results, the Ti2+ cations at the [B] sites constitute about 81% of the total Ti content x for all samples, which is close to the content of the Ni2+ cations at the [B] sites (77%).