Mild intramolecular P–C(sp3) bond cleavage in bridging diphosphine complexes of RuII RhIII and IrIII

Three new carboxylic acid functionalised diphosphines, R2PCH2N(Ar)CH2PR2 [CyL1 R = Cy, Ar = (1-CO2H)(3-OMe)C6H3, CyL2R = Cy, Ar = (1-CO2H)(3-OH)C6H3 and PhL3 R = Ph, Ar = (1-CO2H)(5-OMe)C6H3] have been prepared from condensation of R2PCH2OH and the appropriate aromatic amine in MeOH, and isolated as...

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Bibliographic Details

Main Authors:	Peter De'Ath, Mark Elsegood, Christopher Halliwell, Martin Smith
Format:	Default Article
Published:	2021
Subjects:	Inorganic chemistry Organic chemistry Other chemical sciences Carboxylic acids P ligands Late-transition metals X-ray crystallography P−C bond cleavage
Online Access:	https://hdl.handle.net/2134/21666098.v1
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