Concise synthesis of moracin M using Appel mediated dehydration of a bioinspired endoperoxide

A synthesis of moracin M using Appel dehydration of a biomimetic inspired endoperoxide and subsequent late stage aromatization, is described. A key 1,3-diene, obtained from a base-free Suzuki-Miyaura coupling, can undergo biomimetic oxidation to its endoperoxide, followed by dehydration under Appel...

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Bibliographic Details
Main Authors: Yassir Al-Jawaheri, Mark Elsegood, Jai Mistry, Marc Kimber
Format: Default Article
Published: 2022
Subjects:
Medicinal and biomolecular chemistry
Organic chemistry
Benzofuran
Endoperoxide
Biomimetic
Moracin
Singlet oxygen
Online Access:https://hdl.handle.net/2134/21749489.v1
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https://hdl.handle.net/2134/21749489.v1

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