Reaction of Ph<sub>2</sub>C(X)(CO<sub>2</sub>H) (X = OH, NH<sub>2</sub>) with [VO(OR)<sub>3</sub>] (R = Et, nPr): structure, magnetic susceptibility and ROP capability

Reaction of [VO(OR)3] (R = Et, nPr) with 2,2’-diphenylglycine afforded the alkoxide-bridged dimers {[VO(OR)(mu-OR)[Ph2C(NH2)(CO2)]}2, whereas use of benzilic acid, in the presence of alkali metals, afforded 16-membered metallocycles {V8(O)4M(OR)8[Ph2C(OH)(CO2)]12} (M =

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Bibliographic Details
Main Authors: Mollie A Glenister, Josef Frese, Mark Elsegood, Angelos B Canaj, Euan K Brechin, Carl Redshaw
Format: Default Article
Published: 2024
Subjects:
Online Access:https://hdl.handle.net/2134/25323931.v1
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