Vanadium(v) tetra-phenolate complexes: synthesis, structural studies and ethylene homo-(co-) polymerization capability

Reaction of the ligand α,α,α′,α′-tetrakis(3,5-di-tert-butyl-2-hydroxyphenyl)-p-xylene (p-L1H4) with two equivalents of [VO(OR)3] (R = nPr, tBu) in refluxing toluene afforded, after work-up, the complexes {[VO(OnPr)(THF)]2(-p-L1)}·2(THF) (1·2(THF)) or {[VO(OtBu)]2(-p-L1)}·2MeCN (2·2MeCN), respectiv...

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Bibliographic Details

Main Authors:	Carl Redshaw, Mark J. Walton, Mark Elsegood, Timothy J. Prior, Kenji Michiue
Format:	Default Article
Published:	2015
Subjects:	Other chemical sciences not elsewhere classified Vanadium Tetra-phenolate Ethylene/propylene copolymer Crystal structures Polyethylene Chemical Sciences not elsewhere classified
Online Access:	https://hdl.handle.net/2134/20130
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