The regioselective outcome of ring rearrangement metathesis transformations performed on bicyclo[2.2.2]oct-2-ene derivatives

Treatment of bicyclo[2.2.2]oct-2-en-7-one with organometallic reagents gives the addition products in good yield and moderate diastereoselectivities in favour of the syn-products. Subsequent exposure of these addition products to ruthenium catalysed ring rearrangement metathesis (RRM) conditions rev...

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Bibliographic Details

Main Authors:	Patricia E. Standen, Marc Kimber
Format:	Default Article
Published:	2013
Subjects:	Organic chemistry not elsewhere classified Other chemical sciences not elsewhere classified Bicyclic Grignard Ruthenium Metathesis Rearrangement Chemical Sciences not elsewhere classified Organic Chemistry
Online Access:	https://hdl.handle.net/2134/13933
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