Molybdenum (Vi) imido complexes derived from chelating phenols: synthesis, characterization and ɛ-caprolactone rop capability

Reaction of the bulky bi-phenols 2,2′-RCH[4,6-(t-Bu)2C6H2OH]2 (R = Me L1MeH2, Ph L1PhH2) with the bis(imido) molybdenum(VI) tert-butoxides [Mo(NR1)(NR2)(Ot-Bu)2] (R1 = R2 = 2,6-C6H3-i-Pr2; R1 = t-Bu, R2 = C6F5) afforded, following the successive removal of tert-butanol, the complexes [Mo(NC6H3i-Pr2-...

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Bibliographic Details

Main Authors:	Yahya Al-Khafaji, Timothy J. Prior, Mark Elsegood, Carl Redshaw
Format:	Default Article
Published:	2015
Subjects:	Other chemical sciences not elsewhere classified Molybdenum (VI) Imido Phenolate Chelate Crystal structures ε-caprolactone Ring opening polymerization Chemical Sciences not elsewhere classified
Online Access:	https://hdl.handle.net/2134/19718
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