Synthesis of fluorinated fused benzofurans and benzothiophenes: smiles-type rearrangement and cyclisation of perfluoro(het)aryl ethers and sulfides

Lithium–bromine exchange in 2-bromophenyl perfluoroaryl ethers or sulfides affords fused fluorinated benzofurans or benzothiophenes respectively by SNAr substitution of the adjacent fluorine in the perfluoroaryl substituent. The structures of the new compounds were confirmed by NMR spectroscopy and...

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Bibliographic Details
Main Authors: Julia Ponce Gonzalez, Mark Edgar, Mark Elsegood, George Weaver
Format: Default Article
Published: 2011
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Online Access:https://hdl.handle.net/2134/11881
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