Chiral counterion strategy in Cu-catalyzed asymmetric allylic oxidation of linear alkenes

Application of a chiral counter-ion strategy in the Kharasch-Sosnovsky reaction is reported. Copper(I) phosphates obtained from axially chiral, BINOL-derived phosphoric acids were investigated as catalysts in the enantioselective allylic oxidation of acyclic alkenes. Good yields and high regioselect...

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Bibliographic Details
Main Authors: Celia A. Incerti-Pradillos, Daniel Hudson, Andrei Malkov
Format: Default Article
Published: 2015
Subjects:
Other chemical sciences not elsewhere classified
Allylic oxidation
Allylic esters
Asymmetric catalysis
Chiral counterion
Chiral phosphates
Regioselectivity
Chemical Sciences not elsewhere classified
Online Access:https://hdl.handle.net/2134/21319
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