Alternating α-olefin distributions via single and double insertions in chromium-catalyzed ethylene oligomerization

The catalytic oligomerization of ethylene with chromium-based complexes containing bis(benzimidazolemethyl)amine (BIMA) ligands results in alternating distributions of linear α-olefins (LAOs). Extremely high activities are obtained (>100 000 g mmol–1 h–1 bar–1) with N-alkyl-substituted BIMA ligan...

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Main Authors: Atanas K. Tomov, James D. Nobbs, Juan J. Chirinos, Prabhjot K. Saini, Robert Malinowski, Sarah K.Y. Ho, Craig T. Young, David S. McGuinness, Andrew J.P. White, Mark Elsegood, George J.P. Britovsek
Format: Default Article
Published: 2016
Subjects:
Inorganic chemistry not elsewhere classified
Organic chemistry not elsewhere classified
Other chemical sciences not elsewhere classified
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Chemical Sciences not elsewhere classified
Inorganic Chemistry
Organic Chemistry
Online Access:https://hdl.handle.net/2134/23530
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https://hdl.handle.net/2134/23530

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