Manganese coordination chemistry of bis(imino)phenoxide derived [2 + 2] Schiff-base macrocyclic ligands

The [2 + 2] Schiff-base macrocycles [2,2’-(CH2CH2)(C6H4NvCH)2-2,6-(4-RC6H2OH)]2 (IRH2), upon reaction with MnCl2 (two equivalents) afforded the bimetallic complex [Cl3Mn(μ-Cl)Mn(IMeH2)] (1) or the salt complex [Cl3Mn(NCMe)][MnCl(ItBuH2)] (2). Under similar conditions, use of the related [2 + 2] oxy-...

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Bibliographic Details
Main Authors: Wenxue Yang, Ke-Qing Zhao, Bi-Qin Wang, Carl Redshaw, Mark Elsegood, Jiang-Lin Zhao, Takehiko Yamato
Format: Default Article
Published: 2015
Subjects:
Inorganic chemistry not elsewhere classified
Other chemical sciences not elsewhere classified
Macrocyclic ligands
Transition metals
Crystal structures
Manganese
Chemical Sciences not elsewhere classified
Inorganic Chemistry
Online Access:https://hdl.handle.net/2134/21105
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