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Activation of hydrogen peroxide by diphenyl diselenide for highly enantioselective oxaziridinium salt mediated catalytic asymmetric epoxidation
The first reported use of benzeneperseleninic acid as a catalytic mediator for oxaziridinium ion catalysed epoxidation is described, providing reaction rates and ee values (up to 85%) similar to those reported when using oxone as the stoichiometric oxidant. A dual catalytic cycle is proposed, in whi...
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Main Authors: | , , , , |
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Format: | Default Article |
Published: |
2013
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Subjects: | |
Online Access: | https://hdl.handle.net/2134/13944 |
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