Activation of hydrogen peroxide by diphenyl diselenide for highly enantioselective oxaziridinium salt mediated catalytic asymmetric epoxidation

The first reported use of benzeneperseleninic acid as a catalytic mediator for oxaziridinium ion catalysed epoxidation is described, providing reaction rates and ee values (up to 85%) similar to those reported when using oxone as the stoichiometric oxidant. A dual catalytic cycle is proposed, in whi...

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Bibliographic Details
Main Authors: Benjamin Buckley, Claire Elliott, Yohan Chan, Nicholas Dreyfus, Philip C. Bulman Page
Format: Default Article
Published: 2013
Subjects:
Organic chemistry not elsewhere classified
Other chemical sciences not elsewhere classified
Epoxidation
Iminium salt
Oxaziridinium
Diphenyl diselenide
Oxidation
Chemical Sciences not elsewhere classified
Organic Chemistry
Online Access:https://hdl.handle.net/2134/13944
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