Molybdocalix[4]arene N,O-Schiff base ligands

The ‘one-pot’ reaction of 2-hydroxy-3,5-di-tert-butylsalicylaldehyde with in-situ generated ‘amino calixarene’ (from {Mo[(2-NC6H4)2CH2CH2]Cl2(DME)}, KOtBu and tbutylcalix[4]areneH4 LH4) afforded, after work-up, the heterobimetallic salt K(NCMe)2[Mo(NCMe)(OEt)(2-C6H4CH2CH2C6H4NH2-2)L] (1∙2MeCN). By c...

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Bibliographic Details
Main Authors: Xue Wang, Ke-Qing Zhao, Mark Elsegood, Carl Redshaw
Format: Default Article
Published: 2017
Subjects:
Other chemical sciences not elsewhere classified
Molybdenum
Calixarene
Schiff base
Molecular structures
Chemical Sciences not elsewhere classified
Online Access:https://hdl.handle.net/2134/27465
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