Atropo- and diastereoselective construction of tetracyclic biphenylazepinium salts derived from aminoalcohols: use as catalysts in enantioselective asymmetric epoxidation.

A range of new biphenylazepinium salt organocatalysts effective for asymmetric epoxidation has been developed incorporating an additional substituted oxazolidine ring, and providing improved enantiocontrol in alkene epoxidation over the parent structure. Starting from enantiomerically pure aminoalco...

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Bibliographic Details
Main Authors: Philip C. Bulman Page, Christopher A. Pearce, Yohan Chan, Phillip Parker, Benjamin Buckley, Gerasimos A. Rassias, Mark Elsegood
Format: Default Article
Published: 2015
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Online Access:https://hdl.handle.net/2134/18878
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