Enabling the rearrangement of unactivated allenes to 1,3-dienes by use of a palladium (0)/boric acid system

A redox neutral rearrangement of an allene to a 1,3-diene by means of a unique palladium hydride complex is reported. The palladium hydride complex is generated from a simple Pd0 source and boric acid (B(OH)3), which is typically identified as a waste by-product of the Suzuki-Miyaura reaction. A mec...

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Bibliographic Details

Main Authors:	yassir Al-Jawaheri, Matthew C. Turner, Marc Kimber
Format:	Default Article
Published:	2018
Subjects:	Organic chemistry not elsewhere classified Other chemical sciences not elsewhere classified Allene 1,3-diene Palladium Boric acid Palladium-hydride Chemical Sciences not elsewhere classified Organic Chemistry
Online Access:	https://hdl.handle.net/2134/33343
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