The thermodynamics of solid-solid interfaces in systems of fixed mass

The textbook approach to interfacial excess quantities, due to Gibbs, is valid only at fixed volume. In the present work we develop an alternative approach to interfacial excess quantities, valid at fixed mass. For solid-solid interfaces this has several advantages over the Gibbs treatment such as (...

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Bibliographic Details

Main Author:	Stephen Fletcher
Format:	Default Article
Published:	2005
Subjects:	Other chemical sciences not elsewhere classified Thermodynamics of interfaces Maxwell relations Gibbs dividing surface Solid-solid phase transformations Surface energy Surface tension Pressure dependence Chemical Sciences not elsewhere classified
Online Access:	https://hdl.handle.net/2134/6061
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