An intermolecular hydroamination of allenamides with arylamines catalyzed by cationic Au(I) salts

An intermolecular hydroamination of allenamides with arylamines has been achieved under mild Au(I) catalysis conditions delivering allylamino E-enamides stereoselectively and in high yield. The reaction is made possible via a convenient method for conjugated N-acyliminium formation.

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Bibliographic Details
Main Authors: Anthony W. Hill, Mark Elsegood, Marc Kimber
Format: Default Article
Published: 2010
Subjects:
Online Access:https://hdl.handle.net/2134/13947
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