Multimetallic lithium complexes derived from the acids Ph 2 C(X)CO 2 H (X=OH, NH 2 ): Synthesis, structure and ring opening polymerization of lactides and lactones

Reaction of LiOR (R = t-Bu, Ph) with the acids 2,2/-Ph2C(X)(CO2H), X = OH (benzH), NH2 (pdgH) was investigated. For benzH, one equivalent LiOt-Bu in THF afforded [Li(benz)(THF)]2·2THF (1·2THF), which adopts a 1D chain structure. If acetonitrile is used (mild conditions), another solvate of 1 is isol...

Full description

Bibliographic Details

Main Authors:	Yahya Al-Khafaji, Timothy J. Prior, Lynne Horsburgh, Mark Elsegood, Carl Redshaw
Format:	Default Article
Published:	2017
Subjects:	Other chemical sciences not elsewhere classified Benzilic acid Diphenylglycine Lithium Ring opening polymerization Structures Chemical Sciences not elsewhere classified
Online Access:	https://hdl.handle.net/2134/25906
Tags:	Add Tag No Tags, Be the first to tag this record!