Mono- and tetra-nuclear copper complexes bearing bis(imino)phenoxide derived ligands: catalytic evaluation for benzene oxidation and ROP of epsilon-caprolactone

Complexes of the type [Cu(L)2] (1) and [Cu4L2(μ4−O)(OAc)4] (2) have been obtained from the reaction of the phenoxydiimine 1,3-(2,6-R22C6H3N=CH)2-5-R1C6H2OH-2 (LH) (where R1 = Me, tBu, Cl; R2 = Me, iPr) with copper(II) acetate [Cu(OAc)2]; changing the molar ratio of the reactants affords 10 differing...

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Bibliographic Details

Main Authors:	Xue Wang, Ke-Qing Zhao, Mark Elsegood, Timothy J. Prior, Xiaoming Liu, Li Wu, Sergio Sanz, Euan K. Brechin, Carl Redshaw
Format:	Default Article
Published:	2015
Subjects:	Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified
Online Access:	https://hdl.handle.net/2134/18647
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