Highly stereoselective synthesis of z-homoallylic alcohols by kinetic resolution of racemic secondary allyl boronates

α to Z: Racemic α-chiral allyl boronates, which are readily synthesized from the respective primary allyl halides, undergo a highly efficient kinetic resolution in a face- and Z-selective allylation of aldehydes catalyzed by the chiral Brønsted acid (R)-TRIP (see scheme; Epin=tetraethylethylene glyc...

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Bibliographic Details
Main Authors: Celia A. Incerti-Pradillos, Mikhail A. Kabeshov, Andrei Malkov
Format: Default Article
Published: 2013
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Online Access:https://hdl.handle.net/2134/13543
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