Palladium-catalyzed alkoxycarbonylation of terminal alkenes to produce α,β-unsaturated esters: the key role of acetonitrile as a ligand

A mild protocol has been developed for the Pd-catalyzed alkoxycarbonylation of terminal olefins to produce α,β-unsaturated esters with a wide range of substrates. Key features are the use of MeCN as solvent (and/or ligand) to control the reactivity of the intermediate Pd complexes and the combinatio...

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Bibliographic Details

Main Authors:	Andrei Malkov, Nolwenn Derrien, Maciej Barlog, Pavel Kocovsky
Format:	Default Article
Published:	2014
Subjects:	Other chemical sciences not elsewhere classified Carbonylation Homogeneous catalysis Catalysis Oxygen Palladium Solvent effects Chemical Sciences not elsewhere classified
Online Access:	https://hdl.handle.net/2134/15476
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