Iron hexacyanoferrate films : spectroelectrochemical distinction and electrodeposition sequence of 'soluble' (K+-containing) and 'insoluble' (K+-free) Prussian Blue, and composition changes in polyelectrochromic switching

Films of Prussian Blue (PB) deposited by electroreduction in the absence of K + have absorbance maxima at 730 nm which narrow and shift on voltammetric cycling in KCI solution to 690 nm, these absorptions being deemed diagnostic of 'insoluble' and 'soluble' PB respectively. Spect...

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Bibliographic Details
Main Authors: Roger J. Mortimer, David R. Rosseinsky
Format: Default Article
Published: 1984
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Online Access:https://hdl.handle.net/2134/11531
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