The room-temperature stabilization of bicyclo[2.2.2]oct-1-ene and bicyclo[3.2.1]oct-1-ene

Retardation through incarceration: The highly strained anti-Bredt bridgehead olefin bicyclo[2.2.2]oct-1-ene (1) is remarkably stable at 60 °C, if generated photochemically inside the hemicarcerand 2. The surrounding host not only prevents the dimerization of 1, but also retards strongly its intramol...

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Bibliographic Details
Main Authors: Paul Roach, Ralf Warmuth
Format: Default Article
Published: 2003
Subjects:
Other chemical sciences not elsewhere classified
Carbenes
Hemicarcerands
Host–guest systems
Ring expansion
Strained molecules
Chemical Sciences not elsewhere classified
Online Access:https://hdl.handle.net/2134/25357
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https://hdl.handle.net/2134/25357

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