Heterogeneous catalysis in solution. Part 20.1—Catalysis by silver bromide and other solids of the solvolysis of t-butyl bromide in 80 vol% ethanol + water

The SN1 solvolysis of 2-bromo-2-methylpropane (t-butyl bromide) in 80 vol%(55.2 mol%) EtOH + H2O at 25 °C was found to be catalysed by silver and several insoluble silver and mercury salts but not by BaSO4, SiO2 or platinum. The relative catalytic effectiveness of these solids could be largely expla...

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Bibliographic Details
Main Authors: Ester F.G. Barbosa, Roger J. Mortimer, Michael Spiro
Format: Default Article
Published: 1981
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Online Access:https://hdl.handle.net/2134/11537
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