Solution, structural and photophysical aspects of substituent effects in the N^N ligand in [Ir(C^N) 2 (N^N)] + complexes

The syntheses and properties of a series of eleven new [Ir(ppy) 2(N^N)][PF6] complexes (Hppy = 2-phenylpyridine) are reported. The N^N ligands are based on 2,2-bipyridine (bpy), substituted in the 6- or 5-positions with groups that are structurally and electronically diverse. All but two of the N^N...

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Bibliographic Details
Main Authors: Edwin C. Constable, Catherine E. Housecroft, Peter Kopecky, Colin J. Martin, Iain Wright, Jennifer A. Zampese, Henk J. Bolink, Antonio Pertegas
Format: Default Article
Published: 2013
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Online Access:https://hdl.handle.net/2134/25419
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