Experimental evidence for the involvement of dinuclear alkynylcopper(I) complexes in alkyne-azide chemistry

Dinuclear alkynylcopper(I) ladderane complexes are prepared by a robust and simple protocol involving the reduction of Cu2(OH)3OAc or Cu(OAc)2 by easily oxidised alcohols in the presence of terminal alkynes; they function as efficient catalysts in copper-catalysed alkyne–azide cycloaddition reaction...

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Bibliographic Details
Main Authors: Benjamin Buckley, Sandie Dann, Harry Heaney
Format: Default Article
Published: 2010
Subjects:
Other chemical sciences not elsewhere classified
Alkynes
Azides
Catalysis
Click chemistry
Copper
Chemical Sciences not elsewhere classified
Online Access:https://hdl.handle.net/2134/15799
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