Coordination chemistry of aminophosphine ligands
The reaction of [MCl2(cod)] (M = Pt, Pd) with two equivalents of 2-(diphenylphosphinoamino)pyridine, Ph2PNHpy, in warm acetonitrile led to cationic complexes of the type cis-[MCl(Ph2PNHpy-P,N){Ph2PNHpy-P}][Cl] (M = Pt, Pd) which exhibit broad single 31P{1H} NMR resonances due to their dynamic pyridy...
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| Format: | Default Thesis |
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1999
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| Online Access: | https://hdl.handle.net/2134/34492 |
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