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Asymmetric allylation of carbonyl compounds: kinetic resolution of sec-allylboronates and total synthesis of natural products
Asymmetric allylation of aldehydes with stoichiometric allylmetal reagents has evolved into an efficient and well established methodology for the synthesis of enantiomerically enriched homoallylic alcohols. The use of enantioenriched secondary allylboronates gives rise to a mixture of E/Z homoallyli...
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| Format: | Default Thesis |
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2014
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| Online Access: | https://hdl.handle.net/2134/14991 |
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