The intramolecular ene reactions of some unsaturated acyloins
The reaction of 3β-tosyloxy-5α-cholesta-5,6β-diol with potassium t butoxide in t-butanol has been further investigated. 5β-Hydroxy-4,5-secocholest-3-en-6-one was synthesised. It was shown to undergo an ene reaction in decalin in a sealed tube at 200°C to give primarily 3β-methyl-A-nor-5β-cholestan-5...
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| Format: | Default Thesis |
| Published: |
1986
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| Online Access: | https://hdl.handle.net/2134/25592 |
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