New heteroatom ligands and metalla-heterocycles via P–N bond formation
The reaction of K[N{P(S)Ph2}2] (R = Ph or iPr) with [Mo(N3S2)Cl3] in dichloromethane gives [Mo(N3S2){(ph2(O)PNP(S)P2}2] 1 and [Mo(N3S2){iPr2(O)PNP(S)iPr2}2] 2. X-ray crystallography revealed in both compounds the chelates are co-ordinated to octahedral metal centres. The oxygen atoms are located in...
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| Format: | Default Thesis |
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1997
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| Online Access: | https://hdl.handle.net/2134/32271 |
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