Studies towards the total synthesis of the Perophora viridis trithiocane
The influence of solvent and steric hindrance on the conversion of thiolsulfinates to trisulfides with hexamethyldisilathiane was investigated and a new polar mechanism, based on acceleration of the reaction by polar solvents and by fluoride ions, was proposed. The mono and dialkylation of 2,2-disub...
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| Format: | Default Thesis |
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2010
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| Online Access: | https://hdl.handle.net/2134/8577 |
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