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Some aspects of steroidal epoxide rearrangements
The reactions of 5,6α-epoxy-3β-hydroxy-5α-cholestane, 5,6β-epoxy-3β-hydroxy-5β-cholestane, and 5,6α-epoxy-3β-methoxy-5α-cholestane with boron trifluoride etherate in benzene give largely products of rearrangement via C(5)-O cleavage. These results contrast with the known reactions of the correspondi...
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| Format: | Default Thesis |
| Published: |
1971
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| Online Access: | https://hdl.handle.net/2134/27774 |
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