A study of selectivity in the reactions of unsymmetrical trialkylboron compounds

The reaction of disiamylborane with enol acetates derived from an aldehyde bearing two α-hydrogen atoms involves a slow anti-Markownikoff hydroboration followed by rapid elimination and re-hydroboration reactions. Selectivity between reaction of the cis and trans isomers is far smaller than for the...

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Bibliographic Details
Main Author: David W. Payling
Format: Default Thesis
Published: 1967
Subjects:
Online Access:https://hdl.handle.net/2134/36020
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