Aspects of steroidal partial synthesis and rearrangements
The previously reported conversion of 3ß-tosyloxy-5α-cholestane-5, 6ß-diol with Buᵗ0K/Buᵗ0H to 3ß-methyl-A-nor-5ß-cholestan-5-ol-6-one, is believed to arise from a novel intramolecular ene reaction of an intermediate unsaturated acyloin, 4,5-seco-cholest-3-en-6ß-ol-5-one. It was proposed to synthesi...
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| Format: | Default Thesis |
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1982
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| Online Access: | https://hdl.handle.net/2134/26214 |
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